Solvatochromic Shift and Estimation of Dipole Moment of Quinine Sulphate Dication
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چکیده
Absorption and fluorescence spectra of quinine sulphate (QSD) have been recorded at room temperature in wide range of solvents of different polarities. The ground-state dipole moment of QSD was obtained from quantum mechanical calculations and the excited state dipole moment of QSD was estimated from Bakhshiev’s and Kawski-Chamma-Viallet’s equations by means of solvatochromic shift method. Higher value of dipole moment is observed for excited state as compared to the corresponding ground state value and this is attributed to the more polar excited state of QSD. Keywords—Dipole moment, Quinine sulphate dication, Solvatochromic shift
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